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A main-group metal-nonmetal proton bridge catalyst (O−In−S), featuring the In−S polarization pair as asymmetric dual-sites and electronegative oxygen as an electron pool, enables the asymmetric In−S dual-sites to back-donate electrons to the π x * and π y * antibonding orbitals of nitrogen (N 2), achieving exceptional N 2 fixation activity. This discovery paves the way for efficient ...
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Built-in protection.A 1-step synthesis of supported metal phosphides from cheap precursors is described in the Research Article by Constanze N. Neumann ().The approach delivers Ni 2 P/γ-Al 2 O 3 containing surface ligands that protect the noble-metal-free catalyst from air oxidation. Facile displacement of the surface-bound phenyl phosphates by substrate molecules gives rise to catalytic ...
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Angewandte Chemie
Angewandte Chemie publiziert Spitzenforschung aus allen Bereichen der Chemie in einem lesefreundlichen Format. Wöchentliche Updates und Nobelvorträge. Seit 1887 führend.
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Accepted Articles - Angewandte Chemie International Edition - Wiley Online Library