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  1. Jan 6, 2025Now, a Bi(I)-based allyl cation, which can be seen as a heavy congener of all-carbon π-allyl cations, has been reported. This complex serves as a synthon for Bi(I) transfer, enabling access to ...
  2. pubmed.ncbi.nlm.nih.gov

    The chemistry of low-valent bismuth compounds has recently unlocked new concepts in catalysis and unique electronic structure fundamentals. In this work, we describe the synthesis and characterization of a highly reduced bismuth salt featuring a cationic core based on three contiguous Bi(I) centres. …
  3. chemrxiv.org

    based π-allyl cation. Structural, spectroscopic and theoretical analyses validate the unique π-delocalization between the bismuth's highly diffused 6p-orbitals, resulting in a 1.5 bond order between the Bi atoms. This electronic situation places this complex as the heaviest and non-radioactive π-allyl cation of the periodic table.
  4. chemrxiv.org

    Apr 9, 2024The triatomic bismuth-based core holds an electronic situation that mimics the description of the archetypical carbonbased π-allyl cation. Structural, spectroscopic and theoretical analyses validate the unique π-delocalization between the bismuth's highly diffused 6p-orbitals, resulting in a 1.5 bond order between the Bi atoms.
  5. semanticscholar.org

    Jan 6, 2025The chemistry of low-valent bismuth compounds has recently unlocked new concepts in catalysis and unique electronic structure fundamentals. In this work, we describe the synthesis and characterization of a highly reduced bismuth salt featuring a cationic core based on three contiguous Bi(I) centres. The triatomic bismuth-based core exhibits an electronic configuration that mimics the canonical ...
  6. chemrxiv.org

    A trimetallic bismuth-based allyl cation Davide Spinnato, 1 1Nils Nöthling, 1Markus Leutzsch, Maurice van Gastel,1 Lucas Wagner, Frank Neese 1*, and Josep Cornella * 1Max -Planck Institut für Kohlenforschung, Kaiser Wilhelm Platz 1, 45470, Mülheim an der Ruhr, Germany. Correspondence to: neese@kofo.mpg.de; cornella@kofo.mpg.de
  7. The chemistry of low-valent bismuth compounds has recently unlocked new concepts in catalysis and unique electronic structure fundamentals. In this work, we describe the synthesis and characterization of a highly reduced bismuth salt featuring a cationic core based on three contiguous Bi(I) centres. The triatomic bismuth-based core exhibits an electronic configuration that mimics the canonical ...
  8. A trimetallic bismuth(I)-based allyl cation MPG-Autoren Spinnato, Davide Research Group Cornellà, Max-Planck-Institut für Kohlenforschung, Max Planck Society; Nöthling, Nils Service Department Lehmann (EMR), Max-Planck-Institut für Kohlenforschung, Max Planck Society; ...
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